Micellisation
Michael J. Leach
Chemists call certain chemicals ‘surfactant molecules’. When cast adrift in water (an aqueous solution), these chemicals randomly move amidst myriad encircling H2O molecules. Eventually, they come to a critical concentration. Fully immersed & dis - persed in H2O, the separate surfactant molecules start forming close-knit spheres called micelles. This is because: there’s a part there’s a part of each surfactant molecule of each surfactant molecule with this innate fear with this innate love of water. of water. Their hydrophobic tails stay away from the water while their hydrophilic heads face outwards fearlessly. Aggregated in their social spheres, the surfactants start to reduce the tension at the water’s surface. Spontaneously, they emulsify by welcoming insoluble molecules adrift in the aqueous solution into their social spheres. These supramolecular surfactants form emulsions then proceed to perform fantastic feats in the name of health care, cleaning & myriad other applications. For instance, they emerge in household detergents in the realistic hope of one day spiriting insoluble molecules— oils & waxes— away. ‘Micellisation’ first appeared in Consilience.
The science behind the piece:
Micellisation is a dynamic phenomenon whereby individual surfactants — molecules comprising water-loving (hydrophilic) heads and water-fearing (hydrophobic) tails — aggregate in aqueous environments to form multi-molecule (supramolecular) assemblies called ‘micelles’. Micellisation is an act of emergence: the emergence of micelles. In an individual micelle, the hydrophilic heads face outwards to protect the hydrophobic tails from the surrounding water (H₂O) molecules. This provides micelle cores in which poorly water-soluble substances (e.g. oils and waxes) can be sequestered, leading to the formation of emulsions. I learned about micellisation while studying pharmaceutics as part of a Bachelor of Pharmacy degree at La Trobe University, Bendigo. I find it to be a fascinating and inherently poetic topic. This dynamic phenomenon occurs within a range of commercial products, from aqueous injections of vitamins A, D, E and K to various disinfectants and detergents.
Listen to Michael read the poem: